This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Localized corrosion and stress corrosion cracking of stainless steels. Once the crack is initiated, it will propagate rapidly and potentially lead to catastrophic failure. Although the extent and resultant cost of corrosion under insulation cui are not known exactly, j. The secrets of stress corrosion cracking san onofre safety. High performance stainless steels nickel institute. Residual stress is produced by initial metal forming and welding operations although a good welding procedure will avoid this problem by properly annealing the heated area. Chloride stress corrosion cracking and 316 stainless steel. For chloride stress corrosion cracking to occur in stainless steels there must be. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Yes the nace mr 0175 iso 15156 addresses only hydrogen sulfide stress corrosion cracking also called hydrogen stress cracking,and a dozen other names. This is a report on a study to assess quantitatively stress corrosion cracking of ti in alcohol solutions. Two classic cases of stress corrosion cracking are seasonal cracking of brass in.
The surface concentration of hydrogen, oxygen, the hydroxide, and chloride. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Next months final article in the series will cover nickel alloy performance in sulfuric, phosphoric, and nitric acids. Chloride stress corrosion cracking in austenitic stainless. Stress corrosion cracking behavior of nickel base alloys. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. The stress corrosion cracking of type 316 stainless steel in.
Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows. Sensitized austenitic stainless steel suffers stress corrosion cracking scc in. Stress corrosion cracking international institute of. Stress corrosion cracking of steel in liquefied ammonia. Role of the chloride ion in iron corrosion corrosion. Chloride scc is clearly the bane of austenitic stainless steels and one of the main reasons they are not the miracle cure for many corrosion problems. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. For example, galvanic corrosion, which can occur when two dissimilar metals with different oxidation potentials are in electrical contact. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Some copperbased alloys such as aluminum brass are subject to stress corrosion cracking in the presence of ammonia. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking in a brewery paul mueller company. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e.
Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Slow strain rate stress corrosion tests have been performed on type 316 stainless steel in. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Although the type of corrosion most of us are familiar with involves molecular oxygen, corrosion, in general, does not require the presence of free oxygen. Toward understanding the effects of strain and chloride deposition density on atmospheric chlorideinduced stress corrosion cracking of type 304 austenitic stainless steel under mgcl2 and fecl3. In practice, this prevents their use in the airremoval section of power plant condensers. Chemical and electrochemical conditions within stress. They are often selected for flue gas cleaning equipment handling acid. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. The role of the chloride ion in iron corrosion is assessed from the viewpoint of developing the concept that would lead to a general explanation. Nickel and nickel base alloys are normally resistant to chloride stress corrosion cracking as compared to stainless steels.
Stress corrosion cracking facts and how to reduce the risk. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Chlorideoxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Effects of chloride and oxygen on stress corrosion.
The pitting and stress corrosion cracking of a stable austenitic stainless steel in aqueous chloride environments were investigated using a secondary ion mass spectrometer as the primary experimental technique. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. The alloys comprising of 42 45% nickel will not be attacked in this. Stress corrosion cracking scc of nickelbased alloys. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. This may occur when the part is stressed by an applied load or by a residual stress. Stress corrosion cracking facts and how to reduce the. O b x 256 039 8 g u w abstract hydrogenproducing highpressure electrolysers operating with 40% potassium hydroxide solution and an applied oxygen pressure up to 30 barg have been developed. In fact, the industry owners did not find the austerity of the problems. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
The advantageous effect of nickel on limiting the stress corrosion cracking in boiling 42% mgcl2 is observed. The welding and fabrication characteristics of the corrosionresistant nickel alloys. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. In the instance of chemical attack by water, siliconoxygen bonds bridging the. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Galvanic corrosion, alkaline acidic corrosion, and stresscorrosion cracking have all been known to happen in certain conditions. At the same time stress corrosion cracking of zr was studied because of its similarity in chemical behavior to ti. Delahunt in corrosion control under thermal insulation and fireproofing 1. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Most people have seen the spiderwebbed and lightening array type network of highly branched cracks that is common with chloride cracking of sss. Stress corrosion cracking of stainless steels in high pressure alkaline electrolysers haraldsen, k. The final condition that causes stress corrosion cracking is time. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion.
Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a non magnetic alloy consisting of iron. For example, chloride stress corrosion cracking of austenitic stainless steel. Chloride induced stress corrosion cracking in standard austenitic stainless steels, viz. A corrosive medium especially chloride bearing or hydrogensulphide h 2 s media. When corrosion of a localized nature is anticipated, e. The resistance of various alloys to stress corrosion cracking scc determined by constant load testing in aerated 40% cacl 2, ph 1. It was discovered by the authors that ti is easily attacked by stress corrosion cracking in methanol containing hcl. The higher nickel austenitic grades are generally preferred for severe acid service and for resistance to chloride pitting and stress corrosion cracking. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 sinduced scc. Pdf stress corrosion cracking scc of nickelbased alloys. Austenitic steel is sensitive to this type of corrosion above 60c in the presence of dissolved oxygen.
Aug 22, 2007 chloride stress corrosion cracking cscc is initiation and propagation of cracks in a metal or alloy under tensile stresses and a corrosive environment contains chloride compounds. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking cscc can occur in hot acid. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. One of the conclusions from this work was that internal chloride stress corrosion cracking had not been anticipated because of the perceived total absence of oxygen in process fluids. Thus polycarbonate is sensitive to attack by alkalis, but not by acids. Effects of ph on stress corrosion cracking of 188 stainless. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and. Cold work of materials, dissolved oxygen and chloride in water are crucial factors that accelerate the stress corrosion cracking scc crack growth rate of stainless steel in high temperature water. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. Effects of chloride and oxygen on stress corrosion cracking. There is a synergistic relationship between dissolved oxygen and the chloride level.
The 9010 and 7030 cunis are resistant to chloride and sulphide stress corrosion cracking. The mechanism of scc is shown as a simple representation in figure 1. Chloride stress corrosion cracking cscc is initiation and propagation of cracks in a metal or alloy under tensile stresses and a corrosive environment contains chloride compounds. Cold worked austenitic stainless steel type 316 and 316l were studied in order to obtain their effects on scc crack growth rates in 288 and 325 c. Rr298 chloride stress corrosion cracking of duplex stainless. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Sudden cracking and failure of a component without deformation.
Effects of ph on stress corrosion cracking of 18 8 stainless steel in lowchloride water. C, with a view to avoiding chloride stress corrosion cracking. A similar effect is observed in 18 cr8 ni stainless steels in 4 n h2so4. Intergranular stress corrosion cracking an overview. When alloyed with oxygen or aluminum, transgranular stress corrosion cracking can be induced in laboratory tests in seawater and in many organic. Alloy selection for service in chlorine, hydrogen chloride. Chloride stress corrosion cracking in austenitic stainless steel. To prevent localized corrosion in seawater or where there is a potential for oxygen contamination, an alloy with pren40 is recommended, such as super 25cr or cra 2550e corrosion pits in the presence of tensile stresses may act as stress risers and serve as initiation sites for stress corrosion cracking scc. Stress corrosion cracking the international institute of. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Corrosion failure of aisi4340 steel in oxygencontaining aqueous. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Stress corrosion cracking scc safurex highalloy duplex steel has excellent resistance to chloride induced stress corrosion cracking scc.
Chloride stress corrosion cracking inspectioneering. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Effects of fluoride and other halogen ions on the external. Commercial titanium can suffer intergranular stress corrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. Chloride stress corrosion cracking methods of minimizing.
Chloride oxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. The type of cracking varies with the oxygen and chloride content of the water and the most. Stress corrosion cracking behavior of materials intechopen. Corrosion behavior of inconel 625 heanjia super metals. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems.
Stress corrosion cracking behavior of 4340 steel in. Alloy 825 is more resistant to stress corrosion cracking in chloride solutions. There is no practical way to keep oxygen out of the brewhouse which can be considered a positive for your employees. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Highperformance stainless steels3 as individual grades, may offer optimum performance for a specific requirement. Stress corrosion cracking off ti and zr in hclmethanol. Chloride stress corrosion cracking of duplex stainless steels in the absence of oxygen. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07.
1215 1 360 374 115 1419 1606 1431 489 1376 940 1266 1025 889 235 1025 153 426 1607 988 1147 1251 562 967 683 887 112 1000 1036